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This project intends to use the Mount Denali ice core archive to develop the most comprehensive suite of North Pacific fire and summer climate proxy records since about 2500 years before present. Wildfire is a key component of summer climate in the North Pacific where wildfires are projected to increase with continued summer warming. Studies that combine paleorecords of summer climate and wildfire are therefore critically needed, especially in the North Pacific region where fire recurrence rate and decadal-to-centennial scale climate fluctuations occur over longer time periods than are covered by direct observations. The goal of the proposed research is to improve our understanding of relationships between summertime climate and wildfire activity, focusing especially on the Medieval Climate Anomaly (MCA), when regional temperatures were perhaps as warm as the 20th century. Recent advances now permit the measurement of new fire-related (pyrogenic) compounds in ice cores, enabling the development of a robust fire record capable of rigorous comparison with regional paleoclimate reconstructions. 

This project intends to use the Mount Denali ice core archive to develop the most comprehensive suite of North Pacific fire and summer climate proxy records since about 2500 years before present. Wildfire is a key component of summer climate in the North Pacific where wildfires are projected to increase with continued summer warming. Studies that combine paleorecords of summer climate and wildfire are therefore critically needed, especially in the North Pacific region where fire recurrence rate and decadal-to-centennial scale climate fluctuations occur over longer time periods than are covered by direct observations. The goal of the proposed research is to improve our understanding of relationships between summertime climate and wildfire activity, focusing especially on the Medieval Climate Anomaly (MCA), when regional temperatures were perhaps as warm as the 20th century. Recent advances now permit the measurement of new fire-related (pyrogenic) compounds in ice cores, enabling the development of a robust fire record capable of rigorous comparison with regional paleoclimate reconstructions. 

Abstract. Brown carbon (BrC) consists of particulate organic species that preferentially absorb light at visible and ultraviolet wavelengths. Ambient studies show that as a component of aerosol particles, BrC affects photochemical reaction rates and regional to global climate. Some organic chromophores are especially toxic, linking BrC to adverse health effects. The lack of direct measurements of BrC has limited our understanding of its prevalence, sources, evolution, and impacts. We describe the first direct, online measurements of water-soluble BrC on research aircraft by three separate instruments. Each instrument measured light absorption over a broad wavelength range using a liquid waveguide capillary cell (LWCC) and grating spectrometer, with particles collected into water by a particle-into-liquid sampler (CSU PILS-LWCC and NOAA PILS-LWCC) or a mist chamber (MC-LWCC). The instruments were deployed on the NSF C-130 aircraft during WE-CAN 2018 as well as the NASA DC-8 and the NOAA Twin Otter aircraft during FIREX-AQ 2019, where they sampled fresh and moderately aged wildfire plumes. Here, we describe the instruments, calibrations, data analysis and corrections for baseline drift and hysteresis. Detection limits (3σ) at 365 nm were 1.53 Mm−1 (MC-LWCC; 2.5 min sampling time), 0.89 Mm−1 (CSU PILS-LWCC; 30 s sampling time), and 0.03 Mm−1 (NOAA PILS-LWCC; 30 s sampling time). Measurement uncertainties were 28 % (MC-LWCC), 12 % (CSU PILS-LWCC), and 11 % (NOAA PILS-LWCC). The MC-LWCC system agreed well with offline measurements from filter samples, with a slope of 0.91 and R2=0.89. Overall, these instruments provide soluble BrC measurements with specificity and geographical coverage that is unavailable by other methods, but their sensitivity and time resolution can be challenging for aircraft studies where large and rapid changes in BrC concentrations may be encountered.